番红砗磲外套膜色素提取条件优化及成分分析     

付正祎  刘二田  顾志峰  石耀华  王爱民  吴川良  刘春胜 《海洋科学》2019,43(6):71-77

以番红砗磲(Tridacna crocea)为实验对象,通过单因素对比实验对其外套膜色素的提取条件进行了优化,并利用薄层层析色谱法对色素组成进行了初步分析。结果表明:丙酮和乙醇为适宜的番红砗磲外套膜色素提取剂;使用丙酮为提取剂时,浸提时间为4 h,提取温度为25℃,料液比为1︰40。使用乙醇为提取剂时,浸提时间为4 h,提取温度为30℃,料液比为1︰200;利用薄层色谱法分离外套膜颜色为蓝色和红棕色的番红砗磲外套膜色素后发现,蓝色番红砗磲外套膜色素由9种色素组分构成,红棕色个体番红砗磲外套膜色素由10种色素组分构成。  相似文献   

大洋地幔橄榄岩-铬铁矿中的金刚石和深地幔再循环     

杨经绥 《地质力学学报》2020,26(5):731-741

全球多地蛇绿岩型地幔橄榄岩和铬铁矿中发现微粒金刚石，并在中国西藏南部和俄罗斯乌拉尔北部的蛇绿岩铬铁矿中发现原位产出的金刚石，认为是地球上金刚石的一种新的产出类型，不同于金伯利岩型金刚石和超高压变质型金刚石。它们与呈斯石英假象的柯石英、高压相的铬铁矿和青松矿等高压矿物以及碳硅石和单质矿物等强还原矿物伴生，指示蛇绿岩中的这些矿物组合形成于深度150~300 km或者更深的地幔。金刚石具有很轻的C同位素组成（δ13C-18‰~-28‰），并出现多种含Mn矿物和壳源成分包裹体。研究认为它们曾是早期深俯冲的地壳物质，达到>300 km深部地幔或地幔过渡带后，经历了熔融并产生新的流体，后者在上升过程中结晶成新的超高压、强还原矿物组合，通过地幔对流或地幔柱作用被带回到浅部地幔，由此建立了一个俯冲物质深地幔再循环的新模式。蛇绿岩型地幔橄榄岩和铬铁矿中发现金刚石等深部矿物，质疑了蛇绿岩铬铁矿形成于浅部地幔的已有认识，引发了一系列新的科学问题，提出了新的研究方向。   相似文献   

Asymmetry in oceanic crustal structure of the South China Sea basin and its implications on mantle geodynamics     

Fan Zhang  Xubo Zhang  Weiwei Ding  Tingting Wang  Jian Zhu 《International Geology Review》2020,62(7-8):840-858

ABSTRACT

We investigated the oceanic crustal structure and lithospheric dynamics of the South China Sea (SCS) basin through a comprehensive analysis of residual gravity anomaly and bathymetry combined with seismic constraints and interpretation from geodynamic modelling. We first calculated the residual mantle Bouguer anomaly (RMBA) of the oceanic crustal regions of the SCS by removing from free-air gravity anomaly the predicted gravitational attractions of water-sediment, sediment-crust, and crust-mantle interfaces, as well as the effects of lithospheric plate cooling, using the latest crustal age constraints including IODP Expedition 349 and recent deep-tow magnetic surveys. We then calculated models of the gravity-derived crustal thickness and calibrated them using the available seismic refraction profiles of the SCS. The gravity-derived crustal thickness models correlate positively with seismically determined crustal thickness values. Our analysis revealed that the isochron-averaged RMBA are consistently more negative over the northern flank of the SCS basin than the southern conjugate for magnetic anomaly chrons C8n (~25.18 Ma) to C5Dn (~17.38 Ma), implying warmer mantle and/or thicker crust over much of the northern flank. Computational geodynamic modelling yielded the following interpretations: (1) Models of asymmetric and variable spreading rates based on the relatively high-resolution deep-tow magnetic analysis would predict alternating thicker and thinner crust at the northern flank than the southern conjugate, which is inconsistent with the observed systematically thicker crust on the northern flank. (2) Models of episodic southward ridge jumps could reproduce the observed N-S asymmetry, but only for crustal age of 23.6–20 Ma. (3) Southward migration of the SCS ridge axis would predict slightly thinner crust at the northern flank, which is inconsistent with the observations. (4) Models of higher mantle temperatures of up to 25–50°C or >2% less depleted mantle sources on the northern flank could produce large enough anomalies to explain the observed N-S asymmetries.  相似文献   

Terrestrial heat flow and lithospheric thermal structure in the Chagan Depression of the Yingen-Ejinaqi Basin,north central China     

Yinhui Zuo  Shu Jiang  Shihu Wu  Wei Xu  Jiong Zhang  Renpeng Feng  Meihua Yang  Yongshui Zhou  M. Santosh 《Basin Research》2020,32(6):1328-1346

The Chagan Depression in the Yingen-Ejinaqi Basin, located at the intersection of the Paleo-Asian Ocean and the Tethys Ocean domains is an important region to gain insights on terrestrial heat flow, lithospheric thermal structure and deep geodynamic processes. Here, we compute terrestrial heat flow values in the Chagan Depression using a large set of system steady-state temperature data from four representative wells and rock thermal conductivity. We also estimate the “thermal” lithospheric thickness, mantle heat flow, ratio of mantle heat flow to surface heat flow and Moho temperature to evaluate the regional tectonic framework and deep dynamics. The results show that the heat flow in the Chagan Depression ranges from 66.5 to 69.8 mW/m², with an average value of 68.3 ± 1.2 mW/m². The Chagan Depression is characterized by a thin “thermal” lithosphere, high mantle heat flow, and high Moho temperature, corresponding to the lithospheric thermal structure of “cold mantle and hot crust” type. We correlate the formation of the Yingen-Ejinaqi Basin to the Early Cretaceous and Cenozoic subduction of the western Pacific Plate and the Cenozoic multiple extrusions. Our results provide new insights into the thermal structure and dynamics of the lithospheric evolution in central China.  相似文献   

Geochemical Characteristics and Tectonic Significance of Aoyougou Group Basalts in Western North Qilian     

Yixin Liu  Kexuan Hou  Xin Sha  Zhen Ma  Jinrong Wang 《地球科学进展》2018,33(2):189-205

The North Qilian orogenic belt is a typical plate suture zone, which is studded with numerous different sizes of fragments of micro-continental crust consisting of pre-Sinian metamorphic rocks and the North Qilian orogenic belt provides important study carrier for studying the pre-orogenic tectonic process of the North Qilian. The relatively complete volcanic-clastic-carbonate rocks formation of Zhulongguan Group, Changchengian System, Mesoproterozoic are distributed in the Kawa-Qiqing area, Western North Qilian orogenic belt. Geochemical characteristics of the Aoyougou Group basalts in the North Qilian indicated that the contents of major element were relatively stable, high K₂O contents(4.27%~6.07%), TFe₂O₃(10.49%~13.01%),TiO₂(1.96%~2.90%)and middle MgO(5.37%~6.71%,Mg^# 48~51), CaO(2.57%~5.51%)content. Thus, the Aoyougou Group basalts belong to potassium alkaline basalt. The contents of Cr and Ni of the basalts decreased with the decreasing of Mg^#, and there was a positive correlation between CaO and CaO/Al₂O₃, Furthermore, the Eu anomaly of samples was slightly negative, high contents of high field strength elements (HFSE, Nb, Ta, Ti), and the ratios of Gd/Yb(2.5~3.0), Zr/Y(8.6~10.2), Ta/Yb(0.96~1.23), Ti/Yb(5 074~6 021), Zr/Yb(81~97), Ce/Nb(1.87), Zr/Nb(6.41)indicated that the Aoyougou Group basalts had obvious OIB-type magmatic affinity. In combination with the regional geological background, the study results showed that Aoyougou Group alkaline basalt generated from deep enrichment mantle similar to the source of OIB, with fractional crystallization of olivine and monoclinic pyroxene and a certain degree of contamination of continental crust in the process of magmatism, formed in the background of continental rift, might response to the Proterozoic Columbia supercontinent rifting, which further provides important petrological evidences for the relationship between North China Craton rifting events and Columbia supercontinent rifting during Proterozoic.  相似文献   

西藏雅鲁藏布江缝合带中段日喀则地幔橄榄岩中发现金刚石等异常矿物   总被引：1，自引：0，他引：1  

徐向珍  杨经绥  熊发挥  巴登珠  张仲明  李源 《地质学报》2018,92(7):1389-1400

本文报道了雅鲁藏布江缝合带中段日喀则蛇绿岩地幔橄榄岩中发现与该带东西段蛇绿岩岩体中相似的金刚石和特殊地幔矿物群。日喀则地幔橄榄岩体以方辉橄榄岩为主,含少量二辉橄榄岩和纯橄岩,辉石岩和辉长岩呈脉状产在方辉橄榄岩中。通过重砂分选实验,在465kg的方辉橄榄岩大样中发现了30余种特殊矿物群,包括金刚石、自然金、自然铬、自然铜等自然元素矿物类;碳硅石等碳化物类;方铁矿、赤铁矿、磁铁矿、刚玉、铬尖晶石、金红石、锡石、黑钨矿等氧化物类;镍黄铁矿、方铅矿、辉钼矿、辉锑矿、闪锌矿、毒砂等硫化物类;Ag-Au等合金矿物类;橄榄石、辉石、锆石等硅酸盐岩类;白钨矿等钨酸盐岩类;萤石等氟化物类。金刚石和自然金、自然铬、自然铜连同碳硅石的发现表明岩体存在强还原环境,这套特殊矿物组合指示日喀则地幔橄榄岩可能与雅鲁藏布缝合带其他蛇绿岩一样,经历了深地幔演化过程。  相似文献   

华夏陆块钠质高镁玄武岩地球化学特征及地质意义     

郭恒飞  巫建华  郭国林 《地质论评》2018,64(2):418-434

赣州盆地位于钦杭(钦州—杭州)结合带南侧华夏陆块西部,由晚白垩世早期红色碎屑沉积岩系组成,其底部夹有一套玄武岩,全岩Si O_2含量为46.50%~48.13%,具有钠质高镁特征(Mg O=15.47%~18.24%,Mg~#=74~77,K_2O/Na_2O=0.22~0.39)。稀土元素配分型式表现出轻稀土富集右倾,没有明显的Eu异常的特点,表明岩浆没有明显的斜长石分离结晶作用;微量元素上富集大离子亲石元素,高场强元素特别是Ta、Nb、Ti亏损不明显,Cr、Ni的含量分别为235×10~(-6)~617×10~(-6)、157×10~(-6)~493×10~(-6),与原生岩浆的Cr、Ni含量接近,Ba/Nb值(13.51~23.18)和La/Nb值(0.82~1.03)表明源区有富集地幔组分;Sr—Nd—Pb—O同位素显示出源区性质具有EMⅡ型富集地幔特征。岩石学和地球化学特征表明,玄武岩具有原生岩浆性质,是富集地幔部分熔融的产物。同时为中生代华夏陆块EMⅡ型岩石圈地幔提供了准确的证据。由赣州盆地晚白垩世构造背景和构造环境判别图解可知,本区玄武岩形成于板内拉张环境,可能与古太平洋俯冲条件的转变有关。  相似文献   

不同方法提取马氏珠母贝外套膜胶原蛋白理化性质比较     

林海生  王雯  秦小明  曹文红  章超桦  高加龙  郑惠娜  陈忆宾  伍彬 《广东海洋大学学报》2022,(1)

【目的】系统分析不同方法提取的马氏珠母贝(Pinctada martensii)外套膜胶原蛋白的理化性质及生物学功能。【方法】分别采用酸-酶法和热水法从外套膜中提取得到两种胶原蛋白(A-PSC(Pm)和HSC(Pm)),对其氨基酸组成、微观结构及热变性温度等理化特性进行比较分析。【结果】HSC(Pm)提取率高于A-PSC(Pm);HSC(Pm)中,Gly、Glu与Arg相对含量较高,分别为20.16%、17.57%和10.07%;而A-PSC(Pm)中,Glu、Asp与Arg相对含量为19.67%、11.63%和10.07%;紫外光谱和红外光谱分别显示,两种胶原蛋白均在220 nm左右有强吸收峰,且具有典型的胶原蛋白特征带(酰胺A、B、Ⅰ、Ⅱ和Ⅲ带);扫描电镜结果显示,A-PSC(Pm)呈致密多孔网状结构,HSC(Pm)则基本为薄片状;DSC分析结果表明,HSC(Pm)具有更好的热稳定性。【结论】酸-酶法及热水法提取的胶原蛋白均具有类V型胶原蛋白特性,其结构特征及其理化性质均存在差异,可根据需求选择特定的胶原蛋白提取方法用以开发不同类型的产品。  相似文献   

太行山南段安林地区侵入岩LA-ICP-MS锆石U-Pb年龄、 地球化学特征及其构造意义     

余智慧  吴园园  王巧玲  王剑锋  陈昊龙  王明明  祝少辉  陈春景  王昊  袁要伟  李玉芹 《地质论评》2022,68(3):877-890

太行山南段安林地区中生代侵入岩LA-ICP-MS锆石U-Pb测年表明侵入岩形成于129. 1±1. 0~129. 7±1. 1 Ma,属于早白垩世,与太行山其他地区乃至整个华北地区侵入杂岩体具有相近的形成年代,表明在晚中生代太行山地区与华北地区经历了相同的地球动力学背景和构造环境,即南太行山地区处于华北克拉通岩石圈减薄范围之内。安林地区中生代侵入岩轻稀土总量（LREE平均为113. 71×10-6）明显高于重稀土总量（HREE平均为11. 97×10-6）,具有相对明显的富集轻稀土元素的右倾型配分形式、Eu的弱正异常及大离子亲石元素相对富集的特征,且具有Sr、Ba含量高、Sr/Y、（La/Yb）N比值高的特征,表明壳幔岩浆混合是太行山南段安林地区中生代岩浆作用的主要成因机制。  相似文献   

Source constraints for the young basaltic rocks from the northernmost end of Cappadocian region,Turkey: Melting evidence from peridotite and pyroxenite source domains     

Biltan Kürkcüoğlu  M. Tekin Yürür 《Chemie der Erde / Geochemistry》2022,82(1):125838

Widespread magmatic activity developed in the Middle Miocene in the Cappadocian Region of Central Anatolia in Turkey. Despite several previous studies that focus on the geochemical features of the magmatic rocks, the source components and development of melting conditions are still a matter of debate.Recent basaltic rocks from Karaburna and Gül?ehir (1228 and 96 Ka, respectively, Dogan, 2011) are considered as a part of the Central Anatolian Volcanic Province, situated at the northernmost end of the Cappadocian Region. These lavas have similar large ion lithophile (LIL) (except Rb) and high field strength (HFS) element abundances, however, Karaburna samples are more enriched in HFS elements, and both of the rocks suites reflect HFS depletions relative to the OIB signature.Karaburna and Gül?ehir basalts have low Nb/La (0.45–0.5; 0.35–0.5), Nb/Th (2.75–4.61; 1.26–2.85) values, respectively, suggesting contributions from crustal sources, whereas Zr/Ba ratios of these samples range between 0.32–0.93 and 0.4–0.88 and imply that these rocks appear to be derived from asthenospheric sources. These incompatible element ratios can be attributed to either different geochemical processes, or are related to melting from different source component(s).The ambient mantle source of the Cappadocian region appears to be consistent with spinel peridotite, but this domain is not solely satisfactory to represent the melting conditions in the light of new elemental data. Values of Tb/Yb(N) and Zn/Fe provide new constraints suggesting the magmas were generated from the asthenosphere. Tb/Yb(N) ratio separates garnet – spinel transition Tb/Yb_(N) (>1.8) and Zn/Fe ratio displays separation between the peridotite-derived (Zn/Fe <12) and pyroxenite-derived (13?20) melts.A melting model based on REE ratios and Zn/Fe, Co/Fe, Tb/Yb(N) values indicates that basaltic rocks were not derived from a single source component (peridotite). Instead, those values suggest substantial melting contributions from a pyroxenite source domain, which has not been discussed as a source component in previous studies. Melts, from both of the source domains, with the result of asthenospheric upwelling linked to the downgoing Aegean and Cyprean slabs, are distinct from the alkaline character frequently observed as the final products of recent volcanic activity in the Cappadocian region and also explains the different trace element variations observed in such a small scale.  相似文献